Methyl 5-bromo-6-methylpicolinate

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منابع مشابه

Methyl 5-bromo-6-methyl­picolinate

The title compound, C(8)H(8)BrNO(2), does not show any significant inter-molecular π-π or C-H⋯π inter-actions in the crystal packing except for one weak Br⋯Br [3.715 (1) Å] inter-action.

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Methyl 6-bromo-7-meth­oxy-1,3-benzodioxole-5-carboxyl­ate

The non-H atoms of the title compound, C(10)H(9)BrO(5), are essentially coplanar, with the exception of the ester group [the O=C-O-C torsion angle is -143.4 (3)°].

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Methyl 5-bromo-2-hy­droxy­benzoate

The title compound, C(8)H(7)BrO(3), is almost planar (r.m.s. deviation for the non-H atoms = 0.055 Å). In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into C(6) chains propagating in [010]. Very weak aromatic π-π inter-actions [centroid-centroid distances = 3.984 (5) and 3.982 (5) Å] also occur.

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Methyl 5-bromo-2-chloro­pyridine-3-carboxyl­ate

The title compound, C(7)H(5)BrClNO(2), crystallizes with two independent molecules in the asymmetric unit. In the absence of classical inter-molecular inter-actions, the crystal structure exhibits relatively short inter-molecular Br⋯O distances [3.143 (9) and 3.162 (9)Å].

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(5S,6R)-6-Bromo-6-methyl-5-phenyl-3,4,5,6-tetra­hydro-2H-cyclo­penta­[b]pyran-7-one

The title compound, C(15)H(15)BrO(2), was synthesized by a Brønsted acid-catalysed domino electrocyclization-halogenation reaction. The five-membered ring is essentially planar (r.m.s. deviation 0.006 Å) and forms a dihedral angle of 72.7 (3)° with the attached phenyl ring. The six-membered heterocycle adopts a half-chair conformation. The crystal packing is stabilized by a C-H⋯O contact.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2008

ISSN: 1600-5368

DOI: 10.1107/s1600536808042104